Search results for "Secondary bonds"

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COMMUNICATION. OBSERVATIONS ON THE 121-Sb MÖSSBAUER PARAMETERS OF ANTIMONY (III) COMPOUNDS FEATURING A PYRAMIDAL SbS3SKELETAL UNIT

1991

Abstract A linear correlation between the chemical isomer shift and the quadrupole coupling constant for a number of antimony tris-thiolates has been evidenced. This behaviour can be rationalized on considering a modulation of the s/p character of the lone pair of electrons from the influence of secondary bonds.

Coupling constantChemistryOrganic ChemistryInorganic chemistrychemistry.chemical_elementBiochemistrySecondary bondsInorganic ChemistryCrystallographyAntimonyMössbauer spectroscopyQuadrupoleLinear correlationLone pairUnit (ring theory)Phosphorus, Sulfur, and Silicon and the Related Elements

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